甲醇的脱氢已引起人们很大的兴趣,这是因为产品不含水(与用 O_2氧化脱氢相对照),并且可得到一种稳定的抗凝胶的溶液。如果此吸热反应系在溶液中进行,则反应条件可相当温和,并分离出气态氢。尽管有几种均相催化剂[用于长碳链(≥C_2)的仲醇或伯醇脱氢]已为人们熟知,而甲醇的脱氢只有在光催化条件下才会是高效的。在 Dehydrogenation of methanol has drawn great interest because the product is devoid of water (as opposed to oxydehydrogenation with 02) and a stable solution of antigels is obtained. If this endothermic reaction is carried out in solution, the reaction conditions may be relatively mild, and gaseous hydrogen is separated off. Although several homogeneous catalysts [secondary or primary alcohol dehydrogenation for long carbon chains (≥C_2]] are well known, dehydrogenation of methanol is only efficient under photocatalytic conditions. in