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A novel complex [Ag(NIT3Py)3]?(ClO4)(H2O) has been synthesized and structurally characterized by X-ray diffraction method. It crystallizes in the rhombohedral system, space group R 3 with a = 15.8227(17), b = 15.8227(17), c = 31.445(3) ?, γ = 120°, V = 6817.8(12) ?3, Dc = 1.370 g/cm3, Z = 6, μ = 0.566 mm-1, Mr = 937.18, F(000) = 2916, R = 0.0715, wR = 0.2115 and GOF = 1.086. The structure consists of Ag(NIT3Py)3+ cation moiety, one water molecule and one perchloric ion. The Ag(I) ion is in a trigonal planar coordination environment formed by three nitrogen atoms from three NIT3Py ligand molecules.
A novel complex [Ag (NIT3Py) 3]? (ClO4) (H2O) has been synthesized and structurally characterized by X-ray diffraction. It crystallizes in the rhombohedral system, space group R3 with a = 15.8227 = 15.8227 (17), c = 31.445 (3) ?, γ = 120 °, V = 6817.8 (12)? 3, Dc = 1.370 g / cm3, Z = 6 and μ = 0.566 mm- F (000) = 2916, R = 0.0715, wR = 0.2115 and GOF = 1.086. The structure consists of Ag (NIT3Py) 3 + cation moiety, one water molecule and one perchloric ion. The Ag (I) ion is in a trigonal planar coordination environment formed by three nitrogen atoms from three NIT3Py ligand molecules.