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联吡啶钌[Ru(bpy)_3~(2+)]的光化学始于1972年,它是一种理想的进行激发态电子转移反应的试剂。但迄今其作为光氧化反应敏化剂的研究还不多。根据文献报道,认为它是一种单重态氧的敏化剂。 氧在有机化合物的氧化反应中一般以三种不同的形态出现,即单重态氧,超氧离子以
The photochemistry of Ru (bpy) _3 ~ (2+) bipyridylidene began in 1972 as an ideal reagent for the excited state electron transfer reaction. However, there is not much research on it until now as a photooxidation sensitizer. According to the literature, it is considered a singlet oxygen sensitizer. Oxygen in the oxidation of organic compounds generally appear in three different forms, namely singlet oxygen, superoxide ion to