介绍了以水溶性铑 膦络合物RhCl(CO) (TPPTS) 2 作为催化剂前体在水 /有机两相体系中催化烯烃氢甲酰化反应研究的进展 ,阐述了阳离子表面活性剂的加速作用和介稳态胶束 离子对协同作用机理关系 .通过两相体系中界面分子组装和选择与烯烃分子链长相匹配的表面活性剂 ,设计制备了高区域选择性复合催化剂体系 .当采用双长链表面活性剂与铑 膦络合物组成的复合催化体系时 ,在不搅拌的情况下就显示出极高的催化活性 . The progress of catalytic hydroformylation of olefins with water-soluble rhodium phosphine complex RhCl (CO) (TPPTS) 2 as a catalyst precursor in water / organic two-phase system is introduced. The accelerating effect of cationic surfactants And the metastable micelle ion on the synergy mechanism.The high selectivity catalyst was designed and synthesized by interfacial molecular assembly in the two-phase system and the choice of the surfactant which matched with the molecular chain length of alkene.When the double long chain Surfactant and rhodium-phosphine complex complex catalyst system, without stirring in the case showed very high catalytic activity.