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N-对甲苯磺酰基乙二胺分别与1,11-二碘-3,6,9-三氧杂十一烷和1,14-二碘-3,6,9,12-四氧杂十四烷反应,制得N-(2-对甲苯磺酰胺基乙基)单氮杂-12-冠-4或15-冠-5;当用N-(2-对甲苯磺酰胺基乙基)二乙醇胺与1,11-二对甲苯磺酸酯-3,6,9-三氧杂十一烷反应时,才能获得N-(2-对甲苯磺酰胺基乙基)单氮杂-18-冠-6.从甲醇溶液中培养得N-(2-对甲苯磺酰胺基乙基)单氮杂-12-冠-4单晶,属单斜晶系,P2_1/a空间群;a=1.4229(1)nm,b=0.9595(2)nm,c=1.4564(1)nm,β=102.20(1)°,V=1.9435nm~3,Z=4.最终偏离因子R=0.043.
N-p-toluenesulfonyl ethylenediamine with 1,11-diiodo-3,6,9-trioxaundecane and 1,14-diiodo-3,6,9,12-tetraoxa-10 (2-p-toluenesulfonamidoethyl) monoaza- 12-crown-4 or 15-crown-5; when N- (2-p-toluenesulfonamidoethyl) Diethanolamine is reacted with 1,11-bis-tosylate-3,6,9-trioxaundecane to obtain N- (2-p-toluenesulfonamidoethyl) monoaza- Crown-6. N- (2-p-toluenesulfonamidoethyl) monoaza- 12-crown-4 single crystal grown from methanol solution is monoclinic, P2_1 / a space group; a = 1.4229 (1) nm, b = 0.9595 (2) nm, c = 1.4564 (1) nm, β = 102.20 (1) °, V = 1.9435nm ~ 3 and Z = 4. The final deviation factor R = 0.043.