Vertically standing graphene(VSG) sheets have been fabricated by using plasma enhanced chemical vapor deposition(PECVD) method.The lateral size of VSG nanosheets could be well controlled by varying the substrate temperature.The higher temperature usually gives rise to a smaller sheet size.The wettability of VSG films was tuned between hydrophobicity and hydrophilicity by means of oxygen and hydrogen plasma treatment.The supercapacitor electrode made of VSG sheets exhibited an ideal double-layer-capacitor feature and the specific capacitance reached a value up to 9.62 F·m~(-2). Vertically standing graphene (VSG) sheets have been fabricated by using plasma enhanced chemical vapor deposition (PECVD) method. The lateral size of VSG nanosheets could well be controlled by varying the substrate temperature. The higher temperature usually gives rise to a smaller sheet size. The wettability of VSG films was tuned between hydrophobicity and hydrophilicity by means of oxygen and hydrogen plasma treatment. The supercapacitor electrode made of VSG sheets showed an ideal double-layer-capacitor feature and the specific capacitance reached a value up to 9.62 F · m ~ (-2).