随碳一化学的发展,对过渡金属络合物的研究日益增加.我们曾报导过三核羰基钴簇YCCo_3(CO)_9的合成和催化作用,认为Y基团影响簇的催化性能,而正四面体顶端C原子的变化可能会引起催化性能的更大改变.p.Chini等人曾合成异核簇HFeCo_3(CO)_(12),M.J.May等人经质谱和红外光谱分析推测出该化合物具有如下结构: With the development of carbon chemistry, the research on transition metal complexes is increasing.We have reported the synthesis and catalysis of trinuclear cobalt carbonyl cluster YCCo_3 (CO) _9, we believe that the Y group affects the catalytic performance of the cluster, and positive The change of the C atom at the top of the tetrahedron may cause a greater change in the catalytic properties.p.Chini et al have synthesized the heteronuclear cluster HFeCo_3 (CO) _ (12), MJMay and others by mass spectrometry and infrared spectroscopy to infer that the compound Has the following structure: