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配合物［ｄｐｐｆＮｉ（μ-Ｂｒ）２Ｎｉｄｐｅ］［ＰＦ６］（Ⅰ）由ｄｐｅＮｉＢｒ２和ｄｐｐｆＮｉＢｒ２在Ｔ１ＰＦ６的热甲醇溶液中，透光下合成．ＩＲ和ＨＮＭＲ谱表明为溴桥配合物．ＣＶ图表明稳定性较好，并研究了其电化学反应机理．
The complex [dppfNi (μ-Br) 2Nidpe] [PF6] (Ⅰ) was synthesized under the light transmission by dpeNiBr2 and dppfNiBr2 in hot methanol solution of T1PF6. The IR and HNMR spectra show the bromine bridge complex. The CV graph shows that the stability is good and the electrochemical reaction mechanism is studied.