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通过比保留体积对数值与绝对温度倒数的直线关系,水和甲醇标准曲线的正截距、氘交换以及吸附系数和溶解系数的测定,证明至少对我们的聚合物固定相来说。表面吸附对保留值是决定性的因素。
The linear relationship between the logarithm of the retention volume and the reciprocal of the absolute temperature, the normal intercept of the standard curve of water and methanol, the exchange of deuterium, and the determination of the sorption and dissolution coefficients demonstrate at least for our polymer stationary phase. Surface adsorption is a decisive factor in retention.