Shock properties of liquid argon were measured in the shock pressure up to 46 GPa by employing the two-stage light gas gun. Liquid nitrogen was used as coolant liquid. The cryogenic target system has been improved to compare with the previous work. Shock velocities were measured with self-shorting electrical probes. Impactor velocities were measured with an electrical-magnetic induction system. Mass velocities were obtained by mean of shock impedance matching method. The experimental data shows that the slope of experimental Hugoniot curve of liquid argon begins to decrease above 30 GPa.