Fe-based and Fe/Mo composite amorphous coatings were deposited on the surface of plain carbon steel substrates by atmospheric plasma spraying(APS).With increasing the Mo alloy content,the microstructure of the coatings revealed more dense structure.The porosities of composite coating were all less than those of Fe-based coating due to Mo alloy self-bonding performance.The ML-10 friction and wear tester was employed to investigate the wear behaviors of the coatings under dry sliding conditions.It was found that the mass loss of the resultant coatings decreased with increasing Mo-based powders into the feedstock.This was attributed to the reduction of the delaminations resulting from improved intersplat bond with Mo addition. Fe-based and Fe / Mo composite amorphous coatings were deposited on the surface of plain carbon steel substrates by atmospheric plasma spraying (APS) .With increasing the Mo alloy content, the microstructure of the coatings revealed more dense structure.The porosities of composite coating was all less than those of Fe-based coating due to Mo alloy self-bonding performance. ML-10 friction and wear tester was employed to investigate the wear behaviors of the coatings under dry sliding conditions. It was found that the mass loss of the resulting coatings decreased with increasing Mo-based powders into the feedstock. This was attributed to the reduction of the delaminations resulting from improved interstate bond with Mo addition.