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自Reiss等人于1960年前后创立了定标粒子液体理论以后,首先被Pierotti用来估算非极性气体在水中的溶解度,并将其逐渐发展成为我们今天的定标粒子溶液理论;1969年,Shoor-Gubbins应用Pierotti的上述理论模型来解决一系列非极性气体在不同浓度的KOH溶液中的溶解度问题,结果相当成功;此后,Masterton-Lee等人进一步发展这个理论并将其用来解决任意物质体系的溶解度和盐效应常数等问题,均得到了令人满意的结果。在我国,继黄子卿先生将定标粒子理论用于解决气体溶解度问题之后,该理论引起了
Since Reiss et al. Established the calibrated particle liquid theory before and after 1960, Pierotti was first used to estimate the solubility of nonpolar gases in water and gradually developed into the theory of calibrated particle solution. In 1969, Shoor-Gubbins applied Pierotti’s above theoretical model to solve the problem of the solubility of a series of non-polar gases in different concentrations of KOH solution. The results were quite successful; Masterton-Lee et al. Further developed the theory and used it to solve any The solubility of the material system and salt effect constant and other issues, have been satisfactory results. In our country, following the treatment of gas solubility by Mr. Huang Ziqing’s particle scaling theory, the theory has caused