激光诱导击穿光谱技术对钢中缺陷的快速表征

来源 :冶金分析 | 被引量 : 0次 | 上传用户:Michael_Wong
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
激光诱导击穿光谱技术(LIBS)作为一种快速而简单地检查钢表面缺陷的技术,可直接观测到激光脉冲被聚焦于样品之上而感生的等离子体发射物。一个平凸透镜把斑直径大约为1 mm的光量开关Nd:YAG激光器(脉宽:12 ns;重复频率:10 Hz)辐照聚焦于样品表面,用来烧蚀样品的一部分,形成一个微等离子体。等离子体的发射由光纤传送至帕邢-龙校格装置多色仪(焦距:500 mm)。在已被流入和流出的氩气排空的空间里,样品被安装在一个二维移动台上进行两点分析——常规分析和缺陷分析。通过比较两个分析结果,可检测到缺陷部分有显著信号强度的元素。由不同类型的夹杂物可以检测出典型的元素,由氧化铝可检测出铝,由保护渣可检测出铝、钙、镁、硅和钠,由矿渣可检测出铝、钙和镁。经证实,由LIBS分析得到的结果与EPMA(电子探针)研究得到的结果一致。因此,导致缺陷的夹杂物的类型都能通过LIBS技术确定属性。当涂层被激光烧蚀去掉后,镀锌钢也可以被直接分析出来。包括制样,该项技术评定时间不到半小时,因此在炼钢过程中,可以迅速采取合适措施。 Laser Induced Breakdown Spectroscopy (LIBS) As a technique for quickly and simply inspecting steel surface defects, plasma projectiles can be directly observed where laser pulses are focused on the sample. A plano-convex lens was focused on the sample surface by a light-switch Nd: YAG laser (pulse width: 12 ns; repetition frequency: 10 Hz) with a spot diameter of about 1 mm to ablate a portion of the sample to form a micro-plasma . Plasma emission was sent by optical fiber to a Paschen-Long cell polychrometer (focal length: 500 mm). The sample was installed on a two-dimensional mobile station for two-point analysis - routine analysis and defect analysis in the evacuated argon flow into and out of the sample. By comparing the results of two analyzes, elements with significant signal strength in the defect portion can be detected. Typical elements can be detected by different types of inclusions, aluminum is detectable by aluminum oxide, aluminum, calcium, magnesium, silicon and sodium are detected by mold flux and aluminum, calcium and magnesium are detected by slag. It has been confirmed that the results obtained by LIBS analysis are consistent with those obtained by the EPMA (Electron Probe) study. Therefore, the types of inclusions that cause defects can be determined by the LIBS technique. When the coating is ablated by laser ablation, galvanized steel can also be analyzed directly. Including sample preparation, the technology assessment time of less than half an hour, so the steel making process, you can take prompt and appropriate measures.
其他文献
采用高温固相反应法首次合成了新型红色长余辉发光材料Gd2O2S:Eu3+,Si4+,Ti4+.用X射线粉末衍射(XRD)、扫描电镜(SEM)、分光光度计等对合成产物进行了分析与表征.结果表明:Gd2
基于CCD成像和数字图像处理的小孔检测得到了广泛的应用.通过对小孔成像然后提取小孔边缘,将边缘数据拟合后得到小孔的参数.在常用的拟合方法中,最小二乘法在工程中用最多也
对具有消失矩性质的3带对称正交小波进行参数化,给出正交小波的几个重要性质,同时讨论滤波器系数长度、对称中心点、消失矩和离散矩之间的联系,通过放弃线性方程组中的几个消
建立了采用超高效液相色谱同时测定饮料中4种甜味剂(安赛蜜、糖精钠、甜味素、纽甜)的方法.样品经简单的预处理后,通过ACQUITY UPLCTM BEH C18色谱柱分离,以乙腈-20 mmol/L磷
采用固相法和甘氨酸-硝酸盐法(GNP)分别合成了La0.7Sr0.3Cr0.5Mn0.5O3-δ固体氧化物燃料电池阳极材料:LSCM-S(固相法)和LSCM-G(GNP).扫描电镜分析表明LSCM-G材料粒径比LSCM-S
为了更加有效地对符号间干扰进行自适应补偿,本文提出了一种基于均方误差准则的集粒子云算法EPSA(ensemble particle swarm algorithm).在本算法中,自适应均衡器的每个抽头权
宁夏在第十一次党代会上提出“建设和谐富裕新宁夏、与全国同步进入全面小康社会”的奋斗目标背景下,本文通过对和谐富裕新宁夏建设和回族文化建设互动发展研究,对丰富社会的和
音乐是一门艺术学科,它能陶冶学生情操、培养学生活泼乐观的性格,促进学生身心健康的发展,因此音乐课也深受同学们喜欢。对小学低年级学生进行音乐教育,需要掌握儿童的生理、心理
对超声多波束排水管道内壁检测进行了研究.从超声多波束形成的基本原理出发,叙述了多波束系统的组成,给出了系统总体的设计方案及相关的软、硬件设计.