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氧桥双核钛络合物不仅是一类新型的有机钛络合物,而且是合成具有生物和催化活性的不对称有机钛络合物的重要中间体,从而受到了化学家们的重视。据报道环戊二烯基三氯化钛与水反应可以制备氧桥双核钛络合物,但这一反应易于发生多级水解,反应条件难以控制。
The oxygen bridge binuclear titanium complex is not only a new class of organic titanium complexes, but also an important intermediate for the synthesis of biologically and catalytically active asymmetric organotitanium complexes. Cyclopentadienyl titanium trichloride has been reported to react with water to prepare the bidentate oxygen bridged titanium complex, but this reaction is prone to multistage hydrolysis and the reaction conditions are difficult to control.