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介绍了在10%和30%的氢氧化钠中用聚乙二醇相转移催化苯甲醛的歧化反应。该反应能使苯甲酸的产率提高到90.5%和98.3%。同时还报道了在非相转移催化条件下,苯甲醛在15%至25%的氢氧化钠中,进行歧化反应的实验结果。
The disproportionation of benzaldehyde catalyzed by polyethylene glycol phase transfer in 10% and 30% sodium hydroxide is described. The reaction can increase the yield of benzoic acid to 90.5% and 98.3%. The experimental results of disproportionation of benzaldehyde in 15% to 25% sodium hydroxide under non-phase transfer catalysis were also reported.