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The chiral molecule (+)-N-[(3S)-3-(4-fluorophenyl)heptanoyl]bornane-10,2-sultam (C23H32FNO3S, Mr = 421.56), a fluorine-containing derivative of camphorsultam, was conveniently obtained and crystallized in the orthorhombic space group P212121 with a = 7.9044(11), b = 11.6680(16), c = 24.899(3) , V = 2296.4(5) 3, Z = 4, Dc = 1.219 Mg/m3, λ = 0.71073 , μ(MoKα) = 0.172 mm-1 and F(000) = 904. X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat conformation (Fig. 1). The planes constructed by ((C6), (C7), (C8), (C9)) and ((C4), (C5), (C6), (C9)) form a dihedral angle of 70.3(3)°. The plane of (C1)-(C2)-(C3) forms dihedral angles to the aforementioned planes of 85.9(4) and 89.5(4)°, respectively. The molecules are linked via C-H···O/F interactions.
The chiral molecule (+) - N - [(3S) -3- (4-fluorophenyl) heptanoyl] bornane-10,2- sultam (C23H32FNO3S, Mr = 421.56), a fluorine-containing derivative of camphorsultam, was conveniently obtained and crystallized in the orthorhombic space group P212121 with a = 7.9044 (11), b = 11.6680 (16), c = 24.899 3, V = 2296.4 53, Z = 4, Dc = λ = 0.71073 μ, μ (MoKα) = 0.172 mm -1 and F (000) = 904. X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat conformation (Fig. 1). (C9)) and (C4), (C5), (C6), (C9) form a dihedral angle of 70.3 (3) °. The plane of ( C1) - (C2) - (C3) forms dihedral angles to the planes of 85.9 (4) and 89.5 (4) °, respectively. The molecules are linked via CH · O / F interactions.