【摘 要】
：
The reaction of 6,7-dicyanodipyridoquinoxaline (DICNQ) with AgNO3 in a 1:1 molar ratio by solution method gave a new complex [Ag(DICNQ)2]NO3 1. Single-crystal X
【机 构】
：
State Key Laboratory of Structural Chemistry,Graduate School of the Chnese Academy of Sciences
【基金项目】
：
国家自然科学基金;a Key Project from the CAS;福建省自然科学基金
论文部分内容阅读
The reaction of 6,7-dicyanodipyridoquinoxaline (DICNQ) with AgNO3 in a 1:1 molar ratio by solution method gave a new complex [Ag(DICNQ)2]NO3 1. Single-crystal X-ray diffraction analysis reveals that the complex crystallizes in the space group Ibca of orthorhombic system with eight formula units in a cell. Crystal data for 1: a = 15.7055(17), b = 18.411(2), c = 20.680(2) (A), V = 5979.7(11) (A)3, Z = 8, C32H12AgN13O3, Mr = 734.42, Dc = 1.632 g/cm3, (μ = 0.734 mm-1, F(000) = 2928, S = 1.023 and T = 293(2) K. The final R = 0.0659 and wR = 0.1927 for 2118 observed reflections with I > 2σ(I), and R = 0.0801 and wR = 0.2196 for all data. The complex builds up a packing structure by π-π stacking interactions and shows a luminescent feature.
其他文献
Electroless Ni-P/nano-CeO2 composite coating was prepared in acidic condition,and its microstructure and corrosive property were compared with its CeO2-free cou
A novel anodic oxidization equipment was designed to fabricate a large number of porous anodic alumina (PAA) templates in one time.This approach improved the ef
Protein tyrosine phosphatase 1B (PTPI B) plays an important role as a negative regulator and has been proved to be an effective target for the treatment of type
A new compound has been synthesized under hydrothermal conditions and characterized by IR, elemental analysis, XPS and single-crystal X-ray diffraction analysis
A novel fluorinated polyurethane (FPU) with fluorine-containing pendent groups was prepared by using fluorinated polyether glycol (PTMG-g-HFP) as a soft segment
The catalytic activity of Cu-ZSM-5 in trichloroethylene (TCE) combustion increases with the increasing skeletal Cu amount and however decreases with the increas
A combined detection system involving simultaneous LIF and contactless-conductometric measurements at the same place of the microfluidic chip was described.The
A novel reaction-induced method with the aid of solvent for porous thermosetting epoxy was first carried out.Investigations of pore structure using scanning ele
A new three-dimensional coordination polymer [Mn(2,3-pdc)(H2O)]n (2,3-pdc = pyridine-2,3-dicarboxylate) 1 has been hydrothermally synthesized and structurally c
The interaction of the novel tetra-carboxylphenyl calix[4]arene (TCPC) with the bovine heart cytochrome c (Cc) was first investigated by fluorescence spectrosco