2. 您的位置
3. 首页
4. 期刊论文
5. Synthesis, structures and reaction mechanism of transition metal cluster complexes η<sup>5<

Synthesis, structures and reaction mechanism of transition metal cluster complexes η<sup>5<

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：flapme

【摘 要】

：

The tetrahedral metal-cluster complexes containing alkylcyclopentadienyl ligand η5-RC5H4(CO)2 MCo3(CO)6(μ-CO)3(M = Mo, W; R=CH3, C2H5, n-C4H9, C6H5CH2) have b

【作 者】

：

宋礼成 申金玉 胡青眉 黄小荥 

【机 构】

：

DepartmentofChemistry,NankaiUniversity,Tianjin300071,China,StateKeyLaboratoryofStructuralChemistry,F

【出 处】

：

中国科学：化学英文版

【发表日期】

：

1995年2期

【关键词】

：

DUSTER CORE MoCo3 CLUSTER CORE WCo3 alkylcydopentadienyl reaction mechanism crys 

【基金项目】

：

Project supported by the National Natural Science Foundation of China and the State Key Laboratory of Structural Chemistry

下载到本地 , 更方便阅读

下载此文 赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

The tetrahedral metal-cluster complexes containing alkylcyclopentadienyl ligand η5-RC5H4(CO)2 MCo3(CO)6(μ-CO)3(M = Mo, W; R=CH3, C2H5, n-C4H9, C6H5CH2) have been synthesized by thermal reaction of metal-metal single-bonded compounds [η5-RC5H4(CO)3M]2 with

其他文献

UV-induced self-assembly of the inclusion complexes formed between a long-chain photochromic spiropy

Photochromic spiropyran with a long chain alkyl substitute can form axial complexes with α-, β-, and γ-cyclodextrin, respectively. The complexes show normal

期刊

UV-inducedSELF-ASSEMBLYPHOTOCHROMISMSPIROPYRANcyclodextrininclusioncomplex

Coordination polyhedron growth mechanism model and growth habit of crystals

A new growth mechanism model, coordination polyhedron growth mechanism model, is introduced from the angle of the coordination of anion and cation to each other

期刊

生长机制生长习惯热水的方法growth mechanism growth habit hydrothermal method

Solubilities of benzene, toluene and diphenyl in the t-butyl alcohol + water mixtures and hydrophobi

The solubilitices of benzene, toluene and diphenyl in mixed solvents of t-butyl alcohol (TBA) and water at 283.15, 288.15, 293.15 and 298.15 K have been determi

期刊

HYDROPHOBICinteractionsolubilityBENZENETOLUENEDIPHENYLT-BUTYLalcoholGibb

The quantitative relationship between metal radii, cationic radii and electronic configurations of e

A close relationship has been found between the metal radii, cationic radii and electronic configurations of elements. A unified formula for calculating metal r

期刊

METALRADIUSCATIONICRADIUSelectronicconfigurationPERIODICtable.metal radi

Intermolecular forces between acetylcholine and acetylcholinesterases studied with atomic force micr

With the aid of atomic force microscopy, the intermolecular forces between acetyleholinesterases (AChE) and its natural substrate acetylcholine (ACh) have been

期刊

ATOMICFORCEMICROSCOPYacetylcholinesterasesacetylcholine.atomic force micros

SPC cluster modeling of metal oxides: ways of determining the values of point charges in the embedd

为自我一致地决定点费用的大小在嵌入的簇采用了金属氧化物当模特儿的几个标准被建议了并且调查。这些标准的优点和缺点是 compared.Ab initio 学习被执行了显示出在嵌入的 M

期刊

metalOXIDESCLUSTERsurfaceANALOGYEMBEDDEDCLUSTERMODELSPCCLUSTERmodel.m

Characterization of transient species in laser photolysis of aromatic amino acids using acetone as p

The photochemical processes of aromatic amino acids were investigated in aqueous solution using acetone as photosensitizer by KrF (248 nm) laser flash photolysi

期刊

AROMATICAMINOacidlaserflashPHOTOLYSISTRANSIENTspecieselectrontransfer.

Synthesis and time-resolved absorption spectra of 1,3,3,5,2’-pentamethylspiro[indolinnaphthooxazine]

The title compound 1,3,3,5,2’-pentamethylspirooxazine (I) is synthesized and identified by 1R, 1H NMR and elemental analysis. The time-resolved transient absor

期刊

SPIROOXAZINETIME-RESOLVEDabsorptionSPECTRAphotochromism.spirooxazine time-

ab initio calculation study on vibrational spectra of C₂B<sub>10</su

Geometrical optimization and theoretical calculation of the vibrational frequencies have been performed for C2B10H12, NB11H12 and C2B10Cl by using Gaussian 92 p

期刊

CARBORANEVIBRATIONALspectrumRamanactivityIRintensity.carborane vibration

Correlation between ESR and luminescence of MFX:Eu

The electron spin resonance（ESR）and lumiuescence properties of MFX:Eu（M=Ca,Sr,Ba;X=Cl,Br,I）and correlations between them have been investigated.It has been found th

期刊

ALKALINEearthfluorohalidesEUROPIUMelectronSPINRESONANCEluminescence.alka