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Reactions of CuBr with equimolar PyHBr or γ-MePyHBr afforded two novel one-dimensional bromocuprate (Ⅰ)polymers { (PyH)3[Cu3Br6] } ∞ (1) and { (γ-MePyH) 2[Cu2Br4] } ∞ (2), respectively. Both 1 and 2 were charac-terized by IR, elemental analysis, and X-ray