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Hydrothermal reactions of 5-(tetrazol-5-yl) isophthalic acid with cadmium nitrate/praseodymium nitrate led to two complexes of [Cd_3(TZI)_2(H2_O)_(11)]_n(1) and [Pr(TZI)(H_2O)_5]_n(2). Their structures and properties were determined by X-ray diffraction,