【摘 要】
：
合成了新型邻菲咯啉镁(Ⅱ)配合物 [Mg(H2O)4(phen)](phen)[C6H4(COO)2](H2O, 并对其进行了元素分析、IR、TG、X-射线衍射等表征.单晶衍射结果表明, 该配合物晶体属单斜晶系,
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合成了新型邻菲咯啉镁(Ⅱ)配合物 [Mg(H2O)4(phen)](phen)[C6H4(COO)2](H2O, 并对其进行了元素分析、IR、TG、X-射线衍射等表征.单晶衍射结果表明, 该配合物晶体属单斜晶系, 空间群为P21/c, 晶胞参数:a = 11.873(2), b = 31.992(6), c = 8.144(2)(°A), ( = 93.98(3), V = 3085.9(11)(°A)3, Z = 4, F(000) = 1336, Dc = 1.375 g/cm3, β(MoKα) = 0.120 mm(1.对于6889[ Rint = 0.0264]个独立衍射点, 有3939个可观测点满足(I≥2σ (I)), 最终的偏离因子R = 0.0430, wR = 0.1294.标题配合物由1个邻菲咯啉合镁阳离子[Mg(H2O)4(phen)]2+、1个邻苯二甲酸根阴离子C6H4(COO)2)2-、1个溶剂邻菲咯啉分子和1个结晶水分子组成.中心 Mg(Ⅱ)离子为六配位, 六个配位原子形成畸变的MgN2O4八面体构型.
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