One-step preparation of carbon nanotubes with nickel as the core

来源 :Science China Technological Sciences | 被引量 : 0次 | 上传用户:fuyw118
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CNTs with core-shell structure were successfully synthesized by a microwave-assisted polyol method,and magnetic Ni nanoparticles were employed as a catalyst. The preparation method is fast and simple. The structures,morphology and magnetic properties of the as-synthesized samples were investigated using Raman spectrometer,X-ray diffraction (XRD),transmission electron microscopy (TEM),vibrating sample magnetometer (VSM),respectively. The XRD results suggested that Ni particles used as a catalyst in our experiment were nano-sized. In this paper,magnetic Ni nanoparticles were employed as a catalyst,and an electric spark on metal Ni nanoparticles with the microwave eddy current effect could induce CNTs’ formation with the further reaction. The length of hollow carbon nanotubes was micro-sized and the diameters of most of the CNTs were varying from 18 to 20 nm according to the TEM images. Magnetic measurements demonstrated that CNTs with core-shell structure indicated a characteristic ferromagnetic behavior compared with Ni nanoparticles. CNTs with core-shell structure were successfully synthesized by a microwave-assisted polyol method, and magnetic Ni nanoparticles were employed as a catalyst. The structures, morphology and magnetic properties of the as-synthesized samples were using Raman spectrometer, X-ray diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), respectively. The XRD results suggested that Ni particles used as a catalyst in our experiment were nano-sized. , magnetic Ni nanoparticles were employed as a catalyst, and an electric spark on metal nanoparticles with the microwave eddy current effect could CNTs’ formation with the further reaction. The length of hollow carbon nanotubes was micro-sized and the diameters of the most of the CNTs were varying from 18 to 20 nm according to the TEM images. Magnetic measurements of that CNTs with core-shell structure indicate a characteristic fer romagnetic behavior compared with Ni nanoparticles.
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