Effects of Ca(Y)-Si modifier on interface morphology and solute segregation during directional solid

来源 :Journal of University of Science and Technology Beijing(Engl | 被引量 : 0次 | 上传用户:zhoubear
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The austenite medium Mn steel modified with controlled additions of Ca, Y, Si were directionally solidified using the vertical Bridgman method to study the effects of Ca(Y)-Si modifier on the solid-liquid (S-L) interface morphology and solute segregation. The interface morphology and the C and Mn segregation of the steel directionally solidified at 6.9 μm/s were investigated with an image analysis and a scanning electron microscope equipped with energy dispersive X-ray analysis. The 0.5wt% Ca-Si modified steel is solidified with a planar S-L interface. The interface of the 1.0wt% Ca-Si modified steel is similar to that of the 0.5wt% Ca-Si modified steel, but with larger nodes. The 1.5wt% Ca-Si modified steel displays a cellular growth parttern. The S-L interface morphology of the 0.5wt% Ca-Si+1.0wt% Y-Si modified Mn steel appears as dendritic interface, and primary austenite dendrites reveal developed lateral branching at the quenched liquid. In the meantime, the independent austenite colonies are formed ahead of the S-L interface. A mechanism involving constitutional supercooling explains the S-L interface evolution. It depends mainly on the difference in the contents of Ca, Y, and Si ahead of the S-L interface. The segregation of C and Mn ahead of the S-L interface enhanced by the modifiers is observed. The austenite medium Mn steel modified with controlled additions of Ca, Y, Si were directionally solidified using the vertical Bridgman method to study the effects of Ca (Y) -Si modifier on the solid-liquid (SL) interface morphology and solute segregation. interface morphology and the C and Mn segregation of the steel directionally solidified at 6.9 μm / s were investigated with an image analysis and a scanning electron microscope equipped with energy dispersive X-ray analysis. The 0.5 wt% Ca-Si modified steel is solidified with The interface of the 1.0wt% Ca-Si modified steel is similar to that of the 0.5wt% Ca-Si modified steel, but with larger nodes. The 1.5wt% Ca-Si modified steel displays a cellular growth parttern. The SL interface morphology of the 0.5 wt% Ca-Si + 1.0 wt% Y-Si modified Mn steel appears as dendritic interface, and primary austenite dendrites reveal late lateral branching at the quenched liquid. In the meantime, the independent austenite colonies are formed ahead of the SL interface. A mechanism involving constitutional supercooling explains the SL interface evolution. It depends mainly on the difference in the contents of Ca, Y, and Si ahead of the SL interface. The segregation of C and Mn ahead of the SL interface enhanced by the modifiers is observed.
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