尽管同多化合物和杂多化合物已作为一种新型催化剂应用于工业上,但到目前为止,对于钒的杂多化合物的研究还是很少的。C.M.Flynn Jr;M.T.Pope 1969年第一个合成了以过渡金属作为中心原子的钒的杂多化合物13—钒锰酸盐,从而揭开了研究钒的杂多化合物的新篇章。这个系列的杂多化合物具有特殊的化学计量比,而且被认为可能具有催化活性,因此研究它们具有一定的理论意义和实际意义。 Although heteropoly compounds and heteropoly compounds have been used industrially as a novel catalyst, so far, little research has been done on the heteropoly compounds of vanadium. C.M.Flynn Jr; M.T.Pope In 1969, the first synthesis of heteropoly compound 13-vanadomasite of vanadium with a transition metal as the central atom opened a new chapter in the study of vanadium heteropoly compounds. This series of heteropoly compounds have special stoichiometric ratio, and are considered to have catalytic activity, so the study of them has a certain theoretical and practical significance.