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A novel imidazole-functionalized dioxovanadium complex [V_2O_2(C_2O_4)(aIM)_4](aIM = 1-allylimidazole) was synthesized by the reaction of VO(acac)_2 with 1-allylimidazole and fully characterized by single-crystal X-ray diffraction(SCXRD),powder X-ray diff