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A four-coordinate mononuclear cuprous complex [Cu(ac1m)POP]BF_4·0.5(C_6H_(14))· 0.5(C_2H_5OH)(1, ac1 m = 2-(2-ethoxyphenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline, POP = bis[2-(dipenylphosphino)phenyl]ether) was synthesized and character