【摘 要】
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The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO2 represent an emerging research area in synthetic organic methodology.In particular,the combination of mild reaction conditions,stoichiometric acc
【机 构】
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Dipartimento di Chimica “Giacomo Ciamician”,Alma Mater Studiorum,Università di Bologna,via Selmi 2,4
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The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO2 represent an emerging research area in synthetic organic methodology.In particular,the combination of mild reaction conditions,stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/complexity from readily available unsaturated hydrocarbons and CO2 as a C1-buinding block.The most recent developments in the field have been collected in the present review article and organized,based on the different sets of π-systems/intermediates/reactive partners employed (i.e.,nickelalactones,organo-halides) as well as synthetic strategies (i.e.,visible-light photo redox catalysis).
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