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根据热动力学基础理论和n级反应通用的热动力学方程,本文建立了各种分数级反应的热动力学研究法.应用M-340计算机编制了研究法基本公式中有关无量纲参数的各种函数表,并深入讨论了有关函数的基本性质及其图象.同时将本文建立的分数级反应研究法应用于整数级反应的热动力学研究,所得结果与文献报道的一、二级反应的无量纲参数法基本公式完全相同,该研究法还可用于判断化学反应的级数.
According to the basic theory of thermodynamics and the thermodynamics equation of general n-level reaction, the thermokinetic methods of various fractional reactions were established in this paper.M-340 computer was used to prepare the study of the basic formula of the non-dimensional parameters Function table and discusses the basic properties of the function and its image in depth.Furthermore, the method of fractional reaction established in this paper is applied to the thermokinetic study of integer-level reactions, and the results obtained are in good agreement with those reported in the literature The basic formula of the dimensionless parameter method is exactly the same, the research method can also be used to determine the series of chemical reactions.