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5. Analysis of Hydrolysis Reaction of N-Phosphoryl Phenylalanine by HPLC-ESI-MS/MS

Analysis of Hydrolysis Reaction of N-Phosphoryl Phenylalanine by HPLC-ESI-MS/MS

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：aspoptyy4

【摘 要】

：

Hydrolysis procedure of N-phosphoryl phenylalanine (DIPP-Phe) was studied by HPLC-ESI-MS/MS. The results showed that (HO)(i-PrO)P(O)Phe was the main intermediat

【作 者】

：

Shu Xia CAO Jian Chen ZHANG Ju 

【机 构】

：

The Key Laboratory of Chemical Biology,The Key Laboratory for Bioorganic Phosphorus Chemistry and Ch

【出 处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

N-Phosphoryl amino acids hydrolysis reaction HPLC-ESI-MS 

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论文部分内容阅读

Hydrolysis procedure of N-phosphoryl phenylalanine (DIPP-Phe) was studied by HPLC-ESI-MS/MS. The results showed that (HO)(i-PrO)P(O)Phe was the main intermediate and the hydrolysis of DIPP-Phe also occurred through a penta-coordinate transition state.

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