Synthesis, Crystal Structure, and Biological Activities of 2-Oxo-2-aryl-1-(1,2,4-triazol-1-yl)ethyl

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The two title compounds,2-oxo-2-p-tolyl-1-(1,2,4-triazol-1-yl)ethyl phenylcarbamodithioate(compound 3a) and2-oxo-2-p-biphenyl-1-(1,2,4-triazol-1-yl)ethyl phenylcarbamodithioate(compound 3b), were synthesized and identified by IR, EA and 1H NMR spectra. The crystal structure of compound 3b was determined by X-ray diffraction analysis. The compound crystallized in a monoclinic system of space group P21/c with Mr =398.47(C23H18N4OS),a=0.8769(2) nm,b=1.1924(2) nm, c=2.0440(6) nm,β=109.66(3)°,V=2.0126(8) nm3,Z=4, Dc=1.315 g/cm3, F(000)=832,μ=0.183 mm-1, final R1 =0.0819. The biological test result shows that the two title compounds exhibit certain fungicidal activities.
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