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A novel complex [Na(NIT-1'-MeBzIm)3]ClO4 (NIT-1'-MeBzIm = 2-{2'-[(l'- methyl)benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and structurally characterized by elemental analysis, IR spectra and X-ray diffr