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二茂铁甲酰羟胺衍生物分子中含有N-羟基和α-羰基,可与过渡金属形成螯合物.我们试图将该类螯合物用作复合固体推进剂的燃速调节剂,为此,研究了该类化合物的合成方法及其性质,并使它们与铜(Ⅱ)螯合制成铜螯合物.本文报道7种N-二茂铁甲酰基-芳基羟胺和7种铜螯合物,均未见文献报道.反应式如下:
Ferrocenecarboxylhydroxylamine derivatives contain N-hydroxyl and α-carbonyl groups in their molecules, which can form chelates with transition metals.We tried to use this kind of chelate as the burning rate regulator of composite solid propellant, The synthesis methods and their properties of these compounds have been studied, and they have been chelated with copper (Ⅱ) to form copper chelates.This paper reports seven kinds of N-ferrocene formyl-aryl hydroxylamines and seven kinds of copper chelates , Have not been reported in the literature.The reaction is as follows: