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用光度法测定了桥链冠醚卟啉与Ｃｏ２＋、Ｃｕ２＋配位反应的速率常数、活化能及热力学参数．结果表明：桥链冠醚卟啉与Ｃｏ２＋配位反应活化能Ｅａ较大，△Ｈ＞０；而与Ｃｕ２＋配位反应Ｅｓ较小，且△Ｈ＝０；桥链冠醚钴卟啉的ＥＳＲ谱表明它具有载氧能力．
The rate constants, activation energies and thermodynamic parameters of the coordination reaction of crown ether porphyrin with Co2 + and Cu2 + were determined by spectrophotometry. The results showed that the activation energy Ea of bridged crown ether porphyrin and Co2 + coordination reaction is large, △ H> 0; while the coordination reaction with Cu2 + is small and △ H = 0; the ESR of bridged crown ether porphyrin Spectrum shows it has oxygen carrying capacity.