催化不对称共轭氰化反应是对映选择性构建C—C键、合成手性β-氰基化合物的重要方法,自2003年首次报道以来备受关注.近十年来,对α,β-不饱和二酰亚胺、α,β-不饱和N-酰基吡咯、α,β-不饱和酮、α,β-不饱和酯以及硝基烯的催化不对称共轭氰化反应研究取得了一些重要研究成果.从金属催化和有机催化两方面、以不同Michael受体归类对这一领域的研究进展进行了综述. Catalytic Asymmetric Conjugated Cyanation is an important method for the enantioselective synthesis of C-C bonds and synthesis of chiral β-cyano compounds, and has drawn much attention since it was first reported in 2003. In the past decade, Some studies have been made on the catalytic asymmetric conjugation cyanidation of unsaturated diimides, α, β-unsaturated N-acylpyrroles, α, β-unsaturated ketones, α, β-unsaturated esters and nitroalkylenes The important research results are reviewed from the aspects of metal catalysis and organic catalysis, and the research progress in this field by different Michael acceptors.