Synthesis of unsymmetric triphenylene discotic liquid crystals with a semi-fluorinated chain and the

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The fluorophobic effect of the semi-fluorinated chain of discotic molecules efficiently improves the stability of columnar mesophase.Low symmetric discogens exhibit decreased melting points and wide mesophase ranges.A series of triphenylene derivatives 1,
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[1]Ichikawa M.JPN Patent,JP74116010,1974[2]Li X P,Yu D Y,Han X X,et al.Liquid oxidation of styrene catalyzed by metal phthalocyanines.J Petrochem U (in Chinese)
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