在实验的基础上 ,对氧化气氛下铜的氯化机理进行了研究 ,实验结果证明了铜在氧化气氛下的氯化历程 ,其机理为以O2 为催化剂的循环催化反应 ,并获得了以下动力学参数 :表观反应级数为n =1 ,表观活化能E =3 460J/mol,表观频率因子k0 =1 .9× 1 0 -3 kg/m2 ·s,并获得了铜在氧化气氛下氯化的反应速率方程式 :υ=1 .9× 1 0 -3 exp(-3 460 / (RT) ) (VCl2 % )。 On the basis of experiments, the mechanism of copper chlorination in oxidizing atmosphere was studied. The experimental results proved the chlorination process of copper in oxidizing atmosphere. The mechanism of this reaction was cyclic catalysis with O2 as catalyst, and the following power Learning parameters: Apparent reaction order n = 1, apparent activation energy E = 3 460J / mol, apparent frequency factor k0 = 1.9 × 10 -3 kg / m 2 · s and copper oxidation The reaction rate equation for chlorination in the atmosphere is: ν = 1.9 × 10 -3 exp (-3 460 / (RT)) (VCl 2%).