【摘 要】
：
K(C14H2oO5)2InI4, Mr =1198.16, triclinic,P1,a=ll.839(3), b=12.993(4), c= 14.774(6)A,α=107.87(3),β=109.25(3),γ=95.08(2)°,V=1996.1A3, Z=2, Dc=1.993g.cm-3, Mo
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K(C14H2oO5)2InI4, Mr =1198.16, triclinic,P1,a=ll.839(3), b=12.993(4), c= 14.774(6)A,α=107.87(3),β=109.25(3),γ=95.08(2)°,V=1996.1A3, Z=2, Dc=1.993g.cm-3, MoKa radiation, =0.71073A, F(000)=1136e, R=0.049 for 4381 observable reflections. The structure consists of complex cation K(B15C5)2+ and complex anion InI4-. In the cation, potassium ion lies between two ether oxygen planes of two benzo-15-crown-5 molecules. In the an-ion, indium atom is tetrahedrally coordinated by four iodine atoms.
A = ll.839 (3), b = 12.993 (4), c = 14.774 (6) A, α = 107.87 (3), β = 109.25 (3) ), γ = 95.08 (2) °, V = 1996.1A3, Z = 2, Dc = 1.993 g.cm-3, MoKa radiation, = 0.71073A, F (000) = 1136e, R = 0.049 for 4381 observable reflections. The structure consists of a complex cation K (B15C5) 2+ and complex anion InI4-. In the cation, potassium ion lies between two ether oxygen planes of two benzo-15-crown-5 molecules. tetrahedrally coordinated by four iodine atoms.
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