急性五氯化锑、氯气混合气体中毒2例

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五氯化锑(SbCl_5)中毒临床极少报道,笔者遇见2例由于生产事故而发生中毒者,现报道如下。生产过程锑块加入反应锅,然后再通入氯气(Cl_2),锑、氯气加入量之比约为1:1.46,经反应后形成SbCl_5。病例介绍例1 男,33岁,工人。以吸入SbCl_5及Cl_280分钟急诊入院。80分钟前因生产SbCl_5的反应锅爆炸,致大量SbCl_5及部分Cl_2逸出,现场无人。患者在距爆炸点约20米的房内,接触上述气体后即双眼刺痛、流泪,2分钟后出现黑朦,同时胸闷、气短、呛 Antimony pentachloride (SbCl_5) poisoning clinical rarely reported, I met two cases of poisoning occurred due to production accidents are reported below. Production process of antimony block added to the reaction pot, and then pass into the chlorine (Cl_2), antimony, chlorine added amount of about 1: 1.46, after the reaction to form SbCl_5. Case description 1 male, 33 years old, worker. Inhaled SbCl_5 and Cl_280 minutes emergency admission. 80 minutes ago for the production of SbCl_5 reaction pot explosion, resulting in a large number of SbCl_5 and some Cl_2 escaped, the scene no one. Patient in the room about 20 meters from the explosion point, contact with the gas immediately after the eyes sting, tearing, darkness after 2 minutes, while chest tightness, shortness of breath, choke
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