【摘 要】
：
Under the catalysis of chiral Cu(Ⅱ) complex,C2 and C3 alkylation of pyrrole and C3 alkylation of indole were realized simultaneously.The chiral oxindole skeleton with an all-carbon quaternary stereogenic center at the C3-position could be obtained exclusi
【机 构】
：
Hefei National Laboratory for Physical Sciences at Microscale,Center for Excellence in Molecular Syn
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Under the catalysis of chiral Cu(Ⅱ) complex,C2 and C3 alkylation of pyrrole and C3 alkylation of indole were realized simultaneously.The chiral oxindole skeleton with an all-carbon quaternary stereogenic center at the C3-position could be obtained exclusively with high yields (up to 95％) and excellent enantioselectivities (up to ＞ 99％).
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