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Using Cu(Ⅱ) as the template, a complex {[Cu2L2(H2O)2] 4H2O}n (L = N-acetoxyl-picolinamide) has been successfully synthesized and characterized by single-crystal X-ray diffraction. The crystal is of monoclinic, space group C2/c, with a = 24.144(5), b = 7.1