Effect of Thermal Crosslink Conditions on Dynamic Mechanical Behaviors of Flexible Epoxy

来源 :Journal of Wuhan University of Technology(Materials Science | 被引量 : 0次 | 上传用户:zf524979
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The dynamic mechanical behavior of a new kind of flexible epoxy FE-1,which was crosslinked under four different thermal crosslink conditions,was studied.Dynamic mechanical measurement was carried out from 10 ℃ to 120 ℃,and loss factor,tanδ and the storage modulus as functions of temperature were presented under five different frequencies of 0.1 Hz,1 Hz,5 Hz,50 Hz and 100 Hz.The experimental results show that temperature has dramatic effects on the dynamic mechanical behavior of flexible epoxy.Compared with other common available epoxy,the flexible epoxy has higher loss factor over broad frequency and common temperature range.Activation energy corresponding to glass transition process of FE-1 was calculated from the temperature corresponding to tanδmax values,obtained at different measurement frequencies.The maximum value of loss factor is 0.75 and the Tg varies from 6 ℃ to 50 ℃,indicating the flexible epoxy can be used as damping polymer materials at common temperature or frequency range. The dynamic mechanical behavior of a new kind of flexible epoxy FE-1, which was crosslinked under four different thermal crosslink conditions, was studied. Dynamic mechanical measurement was carried out from 10 ° C to 120 ° C, and loss factor, tanδ and the storage modulus as functions of temperature were presented under five different frequencies of 0.1 Hz, 1 Hz, 5 Hz, 50 Hz and 100 Hz. The experimental results show that temperature has dramatic effects on the dynamic mechanical behavior of flexible epoxy. Compared with other common available epoxy , the flexible epoxy has higher loss factor over broad frequency and common temperature range. Activation energy corresponding to glass transition process of FE-1 was calculated from the temperature corresponding to tan δ max values, obtained at different measurement frequencies 0.75 and the Tg varies from 6 ° C to 50 ° C, indicating the flexible epoxy can be used as damping polymer materials at common temperature or fre quency range.
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