Photoluminescence and thermoluminescence properties of SnO_2 nanoparticles embedded in Li_2O-K_2O-B_

来源 :Chinese Optics Letters | 被引量 : 0次 | 上传用户:lizhuang1022
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Cu-doped borate glass co-doped with SnO2nanoparticles is fabricated by melt quenching.The structure and morphology of the samples are examined by X-ray diffraction and field emission scanning electron microscopy.Up-conversion enhancement is observed in the photoluminescence(PL) and thermoluminescence(TL) intensities of the glass.PL emission spectra are identified in the blue and green regions,and a fourfold increase in emission intensity may be observed in the presence of embedded SnO2nanoparticles.The glow curve is recorded at 215 C,and fourfold increases in TL intensity are obtained by addition of 0.1 mol% SnO2nanoparticles to the glass.Higher TL responses of the samples are observed in the energy range of 15-100 KeV.At energy levels greater than ~0.1 MeV,however,flat responses are obtained.The activation energy and frequency factor of the second-order kinetic reaction are calculated by the peak shape method. Cu-doped borate glass co-doped with SnO2nanoparticles is fabricated by melt quenching. The structure and morphology of the samples are examined by X-ray diffraction and field emission scanning electron microscopy. Up-conversion enhancement is observed in the photoluminescence (PL) and thermoluminescence (TL) intensities of the glass. PL emission spectra are identified in the blue and green regions, and a four fold increase in emission intensity may be observed in the presence of embedded SnO2 nano particles. The glow curve is recorded at 215 C, and four fold increases in TL intensity were obtained by addition of 0.1 mol% SnO2nanoparticles to the glass. Height TL responses of the samples were observed in the energy range of 15-100 KeV. At energy levels greater than ~ 0.1 MeV, however, flat responses are obtained. The activation energy and frequency factor of the second-order kinetic reaction are calculated by the peak shape method.
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