【摘 要】
:
本文制备了不同Fe和Mn含量高真空压铸AlSiMgMn合金,使用透射电镜(TEM)对富Fe相晶体结构和成分进行了分析;使用高分辨三维X射线(3Dμ-CT)对合金进行了断层扫描,获得了富Fe相三维形貌和空间坐标;结合非平衡凝固相变计算,讨论了Fe和Mn含量对富Fe相形成的影响,并分析了初生α-Fe相的生长机理.基于二分Kmeans和DBSCAN方法,设计了空间粒子团簇计算程序,对3Dμ-CT得到的富Fe金属间化合物进行了聚类计算,分析了其团簇定量特征.结果表明:随着Fe含量增加,富Fe相中Fe含量增加;Mn
【机 构】
:
华南理工大学 国家金属材料近净成形工程技术研究中心,机械与汽车工程学院,广州 510640
论文部分内容阅读
本文制备了不同Fe和Mn含量高真空压铸AlSiMgMn合金,使用透射电镜(TEM)对富Fe相晶体结构和成分进行了分析;使用高分辨三维X射线(3Dμ-CT)对合金进行了断层扫描,获得了富Fe相三维形貌和空间坐标;结合非平衡凝固相变计算,讨论了Fe和Mn含量对富Fe相形成的影响,并分析了初生α-Fe相的生长机理.基于二分Kmeans和DBSCAN方法,设计了空间粒子团簇计算程序,对3Dμ-CT得到的富Fe金属间化合物进行了聚类计算,分析了其团簇定量特征.结果表明:随着Fe含量增加,富Fe相中Fe含量增加;Mn含量增加不改变富Fe相的元素含量;两者均不改变富Fe相的晶格常数,但大幅提高富Fe相的形成温度;与平衡凝固相比,高冷却速度下富Fe相和α(Al)相形成顺序改变,对富Fe金属间化合物三维特征和分布产生重要影响,其团簇更为紧密.
其他文献
Rare earth passivation was conducted on Zn coated NdFeB magnets by chemical reaction to enhance the corrosion resistance performance.Morphologies,microstructures and compositions of different passiv-ated coatings were studied by X-ray diffraction,field em
Doping and coating are frequently employed for the improvement of the properties of Ni-rich NCM materials.In this work,we prepared stable LiNi0.8Co0.1Mn0.1O2 (NCM811) materials modified with Y2O3 via a wet chemical method.In order to investigate the actio
Herein,sodium dodecylbenzene sulfonate (SDBS) was used as a template to control the synthesis of Ca0.5Pr0.5FeO3.Its microstructure,composition,and morphology were detected via X-ray diffraction(XRD),Fourier transform infrared spectroscopy (FT-IR),and scan
Due to the increasing criticality of rare earth elements (REEs),it has become essential to recover REEs from alternative resources.In this study,systematic REEs leaching tests were performed on the calci-nation product of a coal coarse refuse using hydroc
Stabilities,mechanical and thermodynamic properties of 87 intermetallics in Al-RE binary system were studied by first-principles based on density functional theory (DFT).The results show that the calculated stabilities at T-0 K are in good agreement with
Solvent extraction is the most important method for rare earth extraction and separation.Currently,di(2-ethylhexyl) phosphoric acid (HDEHP) and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (HEH/EHP) are widely used in industrial production,but the
Mg-Li合金作为目前最轻的金属结构材料,在航空航天、军事、电子产业等领域具有良好的发展前景.但较差的耐蚀性严重制约了Mg-Li合金的广泛应用,因此研究其腐蚀机理和表面防护极为重要.基于国内外的研究进展,综述了Mg-Li合金的腐蚀机理,系统总结了Mg-Li合金的表面防护方法,包括电镀、化学镀、化学转化、阳极氧化、涂层涂覆及其他表面防护方法.建议深入研究各种表面处理方法对Mg-Li合金的防护机理,通过涂层的复合化、自愈化、疏水化来提高涂层对Mg-Li合金的防腐效果.
The recovery of rare earth elements (REEs) from NdFeB slurry by traditional hydrometallurgy has been limited becuase a large number of REEs are lost during separation together with iron.In this paper,a simple and sustainable method is proposed to efficien
研究了时效前的预拉伸变形量对喷射成形2195铝锂合金时效析出行为及力学性能的影响规律.结果表明:2195合金经固溶处理后直接时效,组织以 δ′(Al3Li)相+少量T1(Al2CuLi)相为主,晶界处分布着大量断续分布的颗粒析出相组织(富AlCu相及AlCuFe相).时效前的预拉伸变形在合金基体中引入的大量位错成为T1相、θ′相的有效形核点,显著促进T1相和θ′相晶内均匀、细小弥散析出,并降低晶界无析出带宽度,形成以T1、δ′相、θ′相为主的混合析出相组织.力学性能测试结果表明:当热处理工艺为(510℃,
理解高温熔体(熔盐、液态金属及合金)在碳材料表面的润湿行为对发展高温能源储存与转换、材料铸造与加工、电解冶金、熔盐制备碳等技术十分关键,而目前对这一主题的系统评述还很罕见.本文首先结合实际应用,对常见典型碳材料/高温熔体固?液界面润湿性特点进行了梳理,评述比较了目前常用的三种高温接触角测定方法,随后重点对两类润湿机理进行了讨论:固?液界面非反应的物理润湿和发生化学/电化学反应的反应润湿,以期深化和拓展对于高温熔体在碳表面润湿性的认识,为相关应用提供有关界面润湿的指导.