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The retention and release of deuterium in W–2％Y2O3 composite materials and commercially pure tungsten after they have been implanted by deuterium plasma (fl ux～3.71 × 1021 D/m2·s, energy～25 eV, and fl uence up to 1.3 × 1026 D/m2) are studied. The results show that the total amount of deuterium released from W–2％Y2O3 is 5.23×1020 D/m2(2.5 K/min), about 2.5 times higher than that from the pure tungsten. Thermal desorption spectra (TDS) at different heating rates (2.5 K/min–20 K/min) reveal that both W and W–2％Y2O3 have two main deuterium trapped sites. For the low temperature trap, the deuterium desorption activation energy is 0.85 eV (grain boundary) in W, while for high temperature trap, the desorption activation energy is 1.57 eV (vacancy) in W and 1.73 eV (vacancy) in W–2％Y2O3.