Synthesis and Characterization of Small Band-gap Conjugated Polymers - Poly(pyrrolyl methines)

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:girl_wang
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A kind of small band-gap conjugated polymers-poly (pyrrolyl methines) and their precursors-(poly pyrrolyl methanes) have been synthesized by a simple method and characterized by 1HNMR, FT-IR, TGA and UV-Vis. These polymers can be dissolved in high polar solvents such as DMSO, DMF or NMP. The results reveals that the band-gap of the synthesized conjugated polymers are in the range of 0.96~1.14 eV and they all belong to the small band-gap polymers. The conductivity of doped products with iodine is in the range of semiconductor. A kind of small band-gap conjugated polymers-poly (pyrrolyl methines) and their precursors- (polypyrrolyl methanes) have been synthesized by a simple method and characterized by 1H NMR, FT-IR, TGA and UV-Vis. These polymers can be dissolved in high polar solvents such as DMSO, DMF or NMP. The results reveals that the band-gap of the synthesized conjugated polymers are in the range of 0.96 ~ 1.14 eV and they all belong to the small band-gap polymers. The conductivity of doped products with iodine is in the range of semiconductor.
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