Two new porphyrin-polyoxometalate hybrids,namely,[(C4H9)4N]10H2[{COH NC(CH2O)3P2V3W15O59}2C44N4H28]·CH3CN 1 bearing two covalent-bonded Wells-Dawson type polyoxometalates(POMs)and [(C4H9)4N)]5H[COHNC(
The utilization and transformation of abundant gaseous waste,carbon dioxide as C1 source,into valuable chemical products deserves persistent attentions for the chemists due to the requirement of the g