Monolithic porous metals represent a very sought-after type of structured materials having a number of fascinating properties, which could be extensively utilized in catalysis, electrochemistry, sensing, photovoltaic activity, biological and environmental engineering areas due to their high specific surface areas, large accessible channels and combine the benefits of hierarchical pore structure.In this work, we present the fabrication of porous silver monoliths via thermal treatment for.the prepared silver-based complex.