【摘 要】
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The therapeutic potential of carbon monoxide(CO)has attracted considerable attention despite the general high toxicity to humans due to interaction of this
【机 构】
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College of Chemistry and Life Sciences,Zhejiang Normal University,Jinhua 321004
【出 处】
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2018中西部地区无机化学化工学术研讨会
论文部分内容阅读
The therapeutic potential of carbon monoxide(CO)has attracted considerable attention despite the general high toxicity to humans due to interaction of this odorless and colorless gas with heme proteins.In fact,CO may be an essential signaling molecule similar to NO and H2S in the human body,and shows various physiological functions,e.g.,anti-inflammatory,anti-hypoxia,vasodilatation1-4.How to precisely,safely and controllably deliver CO has been the major concerns in exploiting the medical values of CO4-6.In the present work,four diiron(Ⅱ)carbonyl halides,[Fe2(μ-SR)3(CO)5X](X = I,Br; R = CH2CH3,CH2CH2CH3)were facilely synthesized by the reaction of the same precursor [Fe(CO)4I2] and thiols.
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