钴掺杂对溶剂热合成的磷酸铁锂纳米片电化学性能的影响

来源 :中国化学会第十七次全国电化学大会 | 被引量 : 0次 | 上传用户:l63cn
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  实验通过溶剂热结合酯化反应合成了Co掺杂的一系列LiFe1-xCoxPO4/C (x=0,0.005,0.01,0.015,0.02 and 0.025)纳米片,乙二醇做溶剂.SEM显示所得样品为片状,经TEM显示所得纳米片在b轴方向很短,主要沿(101)晶面的[001]晶向生长,这样缩短了b轴长度,有利于锂离子扩散.电化学测试显示掺杂量为x=0.01的样品LiFe0.99Co0.01PO4/C展示了最好的倍率性能和循环稳定性,0.5 C倍率下初始放电154.5 mAh g-1.并且在10 C放电比容量依旧保持在96.9 mAh g-1.
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