膦-亚磷酰胺酯配体催化α-羰基膦酸酯的不对称催化氢化

来源 :中国化学会全国第十二届有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户:beakerzhou
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  Optically active α-hydroxy phosphonates[1] are an important class of compounds because of their biological and medical activities.Although asymmetric hydrogenation of β-keto phosphonates,α-and β-keto esters has achieved great success,the asymmetric hydrogenation of α-keto phosphonates surprisingly remains scare explored.
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